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Microstate (statistical mechanics)
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Microstate (statistical mechanics) : ウィキペディア英語版
Microstate (statistical mechanics)

In statistical mechanics, a microstate is a specific microscopic configuration of a thermodynamic system that the system may occupy with a certain probability in the course of its thermal fluctuations. In contrast, the macrostate of a system refers to its macroscopic properties, such as its temperature, pressure, volume and density.〔(Macrostates and Microstates )〕 Treatments on statistical mechanics, define a macrostate as follows. A particular set of values of energy, number of particles and volume of an isolated thermodynamic system is said to specify a particular macrostate of it. In this description, microstates appear as different possible ways the system can achieve a particular macrostate.
A macrostate is characterized by a probability distribution of possible states across a certain statistical ensemble of all microstates. This distribution describes the probability of finding the system in a certain microstate. In the thermodynamic limit, the microstates visited by a macroscopic system during its fluctuations all have the same macroscopic properties.
== Microscopic definitions of thermodynamic concepts==
Statistical mechanics links the empirical thermodynamic properties of a system to the statistical distribution of an ensemble of microstates. All macroscopic thermodynamic properties of a system may be calculated from the partition function that sums the energy of all its microstates.
At any moment a system is distributed across an ensemble of N microstates, each denoted by i, and having a probability of occupation p_i, and an energy E_i. If the microstates are quantum-mechanical in nature, then these microstates form a discrete set as defined by quantum statistical mechanics, and E_i is an energy level of the system.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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